Table 3 Analysis of secondary metabolite synthesis in fermented D. officinale juice

organic acids

Succinic acid

116.9854

144.7

C₄H₆O₄

6.19

4.11

6.17

Citric acid

191.0198

153

C₆H₈O₇

6.02

6.35

3.59

trans-Ferulic acid

193.0505

335.5

C₁₀H₁₀O₄

1.12

1.61

1.28

2-Hydroxycinnamic acid

165.0552

504.3

C₉H₈O₃

-

1.98

-

Salicylic acid

137.0238

400.9

C₇H₆O₃

-

0.2

-

Protocatechuic acid

153.0192

828.4

C₇H₆O₄

-

-

1.83

Shikimic acid

173.0454

104.9

C₇H₁₀O₅

-

-

1.44

fatty acids

L-Malic acid

134.0177

77.5

C₄H₆O₅

4.27

2.28

6.3

Methyl jasmonate

207.1373

634.9

C₁₃H₂₀O₃

2.89

6.66

-

Sinapic acid

207.0648

511.9

C₁₁H₁₂O₅

0.88

-

-

Jasmonic acid

193.1219

706.7

C₁₂H₁₈O₃

-

2.33

-

carbohydrates

Trehalose 6-phosphate

421.0747

78.5

C₁₂H₂₃O₁₄P

6.48

7.33

5.8

D-Maltose

342.1391

141.9

C₁₂H₂₂O₁₁

2.2

2.38

-

D-Glucose 1-phosphate

261.0361

90

C₆H₁₃O₉P

-

-

2.41

amino acids

Pipecolic acid

130.0854

142.6

C₆H₁₁NO₂

2.71

-

-

L-Glutamic acid

130.0486

167.9

C₅H₉NO₄

2.22

0.67

-

L-Aspartic acid

132.0304

81.5

C₄H₇NO₄

-

2.86

-

benzene compounds

5-Hydroxyconiferyl alcohol

179.0709

286.6

C₁₀H₁₂O₄

1.29

-

-

(E)-3-(4-Hydroxyphenyl)-2-propenal

131.0488

650.8

C₉H₈O₂

-

3.59

-

Coniferyl alcohol

181.0862

457.3

C₁₀H₁₂O₃

-

0.6

0.96

imidazoles

3-Methylxanthine

166.0496

336.9

C₆H₆N₄O₂

6.94

7.3

7.05

1-Methylxanthine

166.0497

353.3

C₆H₆N₄O₂

2.43

-

2.39

vitamins

alpha-Tocopherol

430.2402

495.7

C₂₉H₅₀O₂

6.9

6.81

6.45

Pantothenic acid

218.1036

195.8

C₉H₁₇NO₅

2.57

2.63

-

terpenoids

Lanosterin

425.2556

814.5

C₃₀H₅₀O

5.28

5.77

-

Sclareol

291.2669

790.6

C₂₀H₃₆O₂

1.89

2.01

1.74

flavonoids

Genistein

271.2257

686

C₁₅H₁₀O₅

4.71

4.41

4.68

Naringenin

271.061

647.1

C₁₅H₁₂O₅

1.66

2.14

-

alkaloid

Ecgonine methyl ester

182.1171

693.7

C₁₀H₁₇NO₃

1.03

1.14

-

ester

Benzoate

121.0294

524.3

C₇H₆O₂

-

-

2.95

other

Geranyl diphosphate

314.0903

250.4

C₁₀H₂₀O₇P₂

-

-

1.91